Study of Neutral Fe(III) Complexes of Pyridoxal-N-Substituted Thiosemicarbazone with Desolvation-Induced Spin-State Transformation above Room Temperature
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چکیده
منابع مشابه
Study of neutral Fe(III) complexes of pyridoxal-N-substituted thiosemicarbazone with desolvation-induced spin-state transformation above room temperature.
The preparation and characterization of two new neutral ferric complexes with desolvation-induced discontinuous spin-state transformation above room temperature are reported. The compounds, [Fe(Hthpy)(thpy)].CH3OH.3H2O (1) and [Fe(Hmthpy)(mthpy)].2H2O (2), are low-spin (LS) at room temperature and below, whereas their nonsolvated forms are high-spin (HS), exhibiting zero-field splitting. In the...
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Four novel mononuclear coordination compounds namely: [Fe(Hthpy)(2)](SO(4))(1/2).3.5H(2)O , [Fe(Hthpy)(2)]NO(3).3H(2)O , [Fe(H(2)mthpy)(2)](CH(3)C(6)H(4)SO(3))(3).CH(3)CH(2)OH and [Fe(Hethpy)(ethpy)].8H(2)O , (H(2)thpy = pyridoxalthiosemicarbazone, H(2)mthpy = pyridoxal-4-methylthiosemicarbazone, H(2)ethpy = pyridoxal-4-ethylthiosemicarbazone), were synthesized in the absence or presence of org...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2007
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic701695b